WebThe halide end-functionality, frequently present on the active chain end(s) of polymers prepared by ATRP, particularly polystyrenes or polyacrylates, can participate in nucleophilic substitution reactions. This strategy has been used for the synthesis of a plethora of end-functional well-defined polymeric materials. Webvarious chain-end functionalized polymers using various functional amines. The reaction with NH2R was utilized for the chain-end transformation of polymer-bromide (Polymer …
High chain-end fidelity in sono-RAFT polymerization - Polymer …
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WebIn this article, the coarse-grained molecular dynamics simulation combined with the stochastic polymerization model was applied to study the preparation of polymer chain-grafted carbon nanotube (CNT) via the “grafting-from” strategy. The simulation results show that it is feasible to promote the grafting density of the polymer … WebThe polymer chain end control model is supported by the observation that highly syndiotactic polypropene is obtained only at low temperatures (about —78°C). Syndiotacticity is significantly decreased by raising the temperature to —40°C [Boor, 1979]. The polymer is atactic when polymerization is carried out above 0°C. 13C NMR analysis of … WebAs a battle-tested senior strategic thinker, I have always prided myself on being a genuine practitioner of Continuous Improvement. I possess an excellent 15+ year track record working within multi-dimensional businesses, where I have applied my commitment to teamwork to build and nurture high performing departments and divisions. I am keen to … d and d monopoly